We can use evrouter for this purpose. You just have to add the following lines to config file ($HOME/.evrouterrc) and modify the key value, the name of your keyboard and event id.
If you don't know how to do it, see my previous post about configuring evrouter.
#audacious jump to song
"Chicony Multimedia Keyboard" "/dev/input/event7" none key/425 "Shell/(audacious -j; sleep 0.2; wmctrl -Fa 'Jump to Song') > /dev/null 2>&1 &"
"Chicony Multimedia Keyboard" "/dev/input/event7" none key/425 "Shell/(audacious -j; sleep 0.2; wmctrl -Fa 'Jump to Song') > /dev/null 2>&1 &"
Note:
audacious -j is for displaying jump to file dialog. After that we need use sleep for a moment, while window manager gets the details of the new window. Now we can activate it with wmctrl command.
(When audacious is closed, the command just opens the program).
Maybe you have to increase sleep value on a slower/busy computer. I tested it with 0.2 second and it worked always.